Dental Materials
Volume 25, Issue 3 , Pages 290-295 , March 2009

A long-term study on the setting reaction of glass ionomer cements by 27Al MAS-NMR spectroscopy

  • Norhazlin Zainuddin

      Affiliations

    • Department of Materials, Imperial College, Imperial College London, South Kensington Campus, London SW7 2AZ, UK
    • Department of Chemistry, Imperial College London, South Kensington Campus, London SW7 2AZ, UK
    • ,
  • Natalia Karpukhina

      Affiliations

    • Department of Materials, Imperial College, Imperial College London, South Kensington Campus, London SW7 2AZ, UK
    • Department of Chemistry, Imperial College London, South Kensington Campus, London SW7 2AZ, UK
    • ,
  • Robert G. Hill

      Affiliations

    • Department of Materials, Imperial College, Imperial College London, South Kensington Campus, London SW7 2AZ, UK
    • Corresponding Author InformationCorresponding author. Tel.: +44 2075945860; fax: +44 2075945804.
    • ,
  • Robert V. Law

      Affiliations

    • Department of Chemistry, Imperial College London, South Kensington Campus, London SW7 2AZ, UK
    • Corresponding Author InformationCorresponding author. Tel.: +44 2075945860; fax: +44 2075945804.

Received 19 March 2008 ,Accepted 18 July 2008.

References 

  1. Wilson AD, Kent BE. New translucent cement for dentistry-glass ionomer cement. Br Dent J. 1972;132:133–135
  2. Jonck LM, Grobbelaar CJ, Strating H. The biocompatibility of glass-ionomer cement in joint replacement: bulk testing. Clin Mater. 1989;4:85–107
  3. Geyer G, Helms J. Ionomer-based bone substitute in otologic surgery. Eur Arch Oto-Rhino-Laryngol. 1993;250:253–256
  4. Forss H. Prevention of enamel demineralization adjacent to glass ionomer filling materials. Scand J Dental Res. 1990;98:173–178
  5. Williams JA, Billington RW. Changes in compressive strength of glass ionomer restorative materials with respect to time periods of 24h to 4 months. J Oral Rehabil. 1991;18:163–168
  6. Crisp S, Pringuer MA, Wardlewo D, Wilson AD. Reactions in glass ionomer cements. 2. Infrared spectroscopic study. J Dental Res. 1974;53:1414–1419
  7. Matsuya S, Maeda T, Ohta M. IR and NMR analyses of hardening and maturation of glass-ionomer cement. J Dental Res. 1996;75:1920–1927
  8. Wasson EA, Nicholson JW. Change in pH during setting of polyelectrolyte dental cements. J Dent. 1993;21:122–126
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  12. Stamboulis A, Law RV, Hill RG. Characterisation of commercial ionomer glasses using magic angle nuclear magnetic resonance (MAS-NMR). Biomaterials. 2004;25:3907–3913
  13. Pires R, Nunes TG, Abrahams I, Hawkes GE, Morais CM, Fernandez C. Stray-field imaging and multinuclear magnetic resonance spectroscopy studies on the setting of a commercial glass-ionomer cement. J Mater Sci-Mater Med. 2004;15:201–208
  14. Hill RG, Stamboulis A, Law RV. Characterisation of fluorine containing glasses by F-19, Al-27, Si-29 and P-31 MAS-NMR spectroscopy. J Dent. 2006;34:525–532
  15. MacKenzie KJD, Smith ME. Multinuclear solid-state NMR of inorganic materials. Pergamon; 2002;
  16. Nicholson JW. Chemistry of glass-ionomer cements: a review. Biomaterials. 1998;19:485–494
  17. Oelkers EH, Schott J, Devidal J-L. The effect of aluminum, pH, and chemical affinity on the rates of aluminosilicate dissolution reactions. Geochim Cosmochim Acta. 1994;58:2011–2024
  18. Griffin SG, Hill RG. Influence of glass composition on the properties of glass polyalkenoate cements. Part II. Influence of phosphate content. Biomaterials. 2000;21:399–403
  19. Stamboulis A, Matsuya S, Hill RG, et al. MAS-NMR spectroscopy studies in the setting reaction of glass ionomer cements. J Dent. 2006;34:574–581
  20. Stebbins JF, Kroeker S, Lee SK, Kiczenski TJ. Quantification of five- and six-coordinated aluminum ions in aluminosilicate and fluoride-containing glasses by high-field, high-resolution Al-27 NMR. J Non-Cryst Solids. 2000;275:1–6
  21. Criscenti LJ, Brantley SL, Mueller KT, Tsomaia N, Kubicki JD. Theoretical and 27Al CPMAS NMR investigation of aluminum coordination changes during aluminosilicate dissolution. Geochim Cosmochim Acta. 2005;69:2205–2220
  22. Dollase WA, Merwin LH, Sebald A. Structure of Na3-3xAlxPO4, x=0 to 0.5. J Solid State Chem. 1989;83:140–149

PII: S0109-5641(08)00198-X

doi: 10.1016/j.dental.2008.07.008

Dental Materials
Volume 25, Issue 3 , Pages 290-295 , March 2009

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