Dental Materials
Volume 25, Issue 1 , Pages 33-38 , January 2009

Evaluation of highly reactive mono-methacrylates as reactive diluents for BisGMA-based dental composites

  • Harini Kilambi

      Affiliations

    • Department of Chemical & Biological Engineering, University of Colorado, 1111 Engineering Drive, CB 424, Boulder, CO 80309, United States
    • ,
  • Neil B. Cramer

      Affiliations

    • Department of Chemical & Biological Engineering, University of Colorado, 1111 Engineering Drive, CB 424, Boulder, CO 80309, United States
    • ,
  • Lauren H. Schneidewind

      Affiliations

    • Department of Chemical & Biological Engineering, University of Colorado, 1111 Engineering Drive, CB 424, Boulder, CO 80309, United States
    • ,
  • Parag Shah

      Affiliations

    • Department of Chemical & Biological Engineering, University of Colorado, 1111 Engineering Drive, CB 424, Boulder, CO 80309, United States
    • ,
  • Jeffrey W. Stansbury

      Affiliations

    • Department of Chemical & Biological Engineering, University of Colorado, 1111 Engineering Drive, CB 424, Boulder, CO 80309, United States
    • Biomaterials Research Center, School of Dentistry, University of Colorado Health Sciences Center, Aurora, CO 80045, United States
    • ,
  • Christopher N. Bowman

      Affiliations

    • Department of Chemical & Biological Engineering, University of Colorado, 1111 Engineering Drive, CB 424, Boulder, CO 80309, United States
    • Biomaterials Research Center, School of Dentistry, University of Colorado Health Sciences Center, Aurora, CO 80045, United States
    • Corresponding Author InformationCorresponding author. Tel.: +1 303 492 3247; fax: +1 303 492 4341.

Received 12 February 2008 ,Revised 25 April 2008 ,Accepted 10 May 2008.

References 

  1. Ferracane JL. Current trends in dental composites. Crit Rev Oral Biol Med. 1995;6:302–318
  2. Peutzfeldt A. Resin composites in dentistry: the resin systems. Eur J Oral Sci. 1997;105:97–116
  3. Khatri CA, Stansbury JW, Schultheisz CR, Antonucci JM. Synthesis, characterization and evaluation of urethane derivatives of Bis-GMA. Dental Mater. 2003;19:584–588
  4. Peutzfeldt A, Asmussen E. Effect of propanal and diacetyl on quantity of remaining double bonds of chemically cured BisGMA/TEGDMA resins. Eur J Oral Sci. 1996;104:309–312
  5. Linden LA, Jakubiak J. Contraction (shrinkage) in polymerization. Part II. Dental resin composites. Polimery. 2001;46:590–595
  6. Burke FJT, Cheung SW. Restoration longevity and analysis of reasons for the placement and replacement of restorations provided by vocational dental practitioners and their trainers in the United Kingdom. Mjor IA, Wilson NH. F.. Quint Int. 1999;30:234–242
  7. Davidson CL, Feilzer AJ. Polymerization shrinkage and polymerization shrinkage stress in polymer-based restoratives. J Dent. 1997;25:435–440
  8. Stansbury JW, Antonucci JM. Evaluation of methylene lactone monomers in dental resins. Dental Mater. 1992;8:270–273
  9. Nie J, Lovell LG, Bowman CN. Synthesis and characterization of N-isopropyl, N-methacryloxyethyl methacrylamide as a possible dental resin. Biomaterials. 2001;22:535–540
  10. Labella R, Davy KWN, Lambrechts P, Van Meerbeek B, Vanherle G. Monomethacrylate co-monomers for dental resins. Eur J Oral Sci. 1998;106:816–824
  11. Decker C, Moussa K. A new class of highly reactive acrylic-monomers. 1. Light-induced polymerization. Macromol Chem Rapid Commun. 1990;11:159–167
  12. Decker C, Moussa K. Photopolymerization of multifunctional polymers. 5. Polyurethane-acrylate resins. Eur Polym J. 1991;27:881–889
  13. Decker C, Moussa K. A new class of highly reactive acrylic-monomers. 2. Light-induced copolymerization with difunctional oligomers. Die Macromol Chem. 1991;192:507–522
  14. Decker C, Moussa K. Photopolymerization of multifunctional monomers. 4. Acrylates with carbamate or oxazolidone structure. Eur Polym J. 1991;27:403–411
  15. Berchtold KA, Nie J, Stansbury JW, Hacioglu B, Beckel ER, Bowman CN. Novel monovinyl methacrylic monomers containing secondary functionality for ultrarapid polymerization: steady-state evaluation. Macromolecules. 2004;37:3165–3179
  16. Kilambi H, Stansbury JW, Bowman CN. Deconvoluting the impact of intermolecular and intramolecular interactions on the polymerization kinetics of ultrarapid mono(meth)acrylates. Macromolecules. 2007;40:47–54
  17. Kilambi H, Beckel ER, Berchtold KA, Stansbury JW, Bowman CN. Influence of molecular dipole on monoacrylate monomer reactivity. Polymer. 2005;46:4735–4742
  18. Kilambi H, Konopka D, Stansbury JW, Bowman CN. Factors affecting the sensitivity to acid inhibition in novel acrylates characterized by secondary functionalities. J Polym Sci A: Polym Chem. 2007;45:1287–1295
  19. Jansen JFGA, Dias AA, Dorschu M, Coussens B. Fast monomers: factors affecting the inherent reactivity of acrylate monomers in photoinitiated acrylate polymerization. Macromolecules. 2003;36:3861–3873
  20. Jansen J, Dias AA, Dorschu M, Coussens B. Effect of preorganization due to hydrogen bonding on the rate of photoinitiated acrylate polymerization. Photoinit Polym. 2003;847:127–139
  21. Lu H, Stansbury JW, Nie J, Berchtold KA, Bowman CN. Development of highly reactive mono-(meth)acrylates as reactive diluents for dimethacrylate-based dental resin systems. Biomaterials. 2005;26:1329–1336
  22. ISO/DIS4049. International organization for standardization. Dentistry-resin based filling materials; 1987. p. 1–13.
  23. Asmussen E. Factors affecting the color stability of restorative resins. Acta Odontol Scand. 1983;41:11–18
  24. Lemon MT, Jones MS, Stansbury JW. Hydrogen bonding interactions in methacrylate monomers and polymers. J Biomed Mater Res A. 2007;83:734–746
  25. Lu H, Lovell LG, Bowman CN. Exploiting the heterogeneity of cross-linked photopolymers to create high-Tg polymers from polymerizations performed at ambient conditions. Macromolecules. 2001;34:8021–8025
  26. Lovell LG, Newman SM, Donaldson MM, Bowman CN. The effect of light intensity on double bond conversion and flexural strength of a model, unfilled dental resin. Dental Mater. 2003;19:458–465

PII: S0109-5641(08)00132-2

doi: 10.1016/j.dental.2008.05.003

Dental Materials
Volume 25, Issue 1 , Pages 33-38 , January 2009

Article Tools

* Image Usage & Resolution