Dental Materials
Volume 24, Issue 10 , Pages 1381-1390 , October 2008

Modification of conventional glass-ionomer cements with N-vinylpyrrolidone containing polyacids, nano-hydroxy and fluoroapatite to improve mechanical properties

  • Alireza Moshaverinia

      Affiliations

    • Department of Materials, Interdisciplinary Research Centre in Biomedical Materials, Queen Mary University of London, Mile End Road, London E1 4NS, UK
  • ,
  • Sahar Ansari

      Affiliations

    • Department of Materials, Interdisciplinary Research Centre in Biomedical Materials, Queen Mary University of London, Mile End Road, London E1 4NS, UK
  • ,
  • Zanyar Movasaghi

      Affiliations

    • Department of Materials, Interdisciplinary Research Centre in Biomedical Materials, Queen Mary University of London, Mile End Road, London E1 4NS, UK
  • ,
  • Richard W. Billington

      Affiliations

    • Department of Biomaterial in Relation to Dentistry, Queen Mary University of London, Mile End Road, London E1 4NS, UK
  • ,
  • Jawwad A. Darr

      Affiliations

    • Department of Chemistry, University College London, Christopher Ingold Laboratories, 20 Gordon Street, London WC1H 0AJ, UK
  • ,
  • Ihtesham U. Rehman

      Affiliations

    • Department of Materials, Interdisciplinary Research Centre in Biomedical Materials, Queen Mary University of London, Mile End Road, London E1 4NS, UK
    • Corresponding Author InformationCorresponding author: Tel.: +44 20 7882 5502; fax: +44 20 8983 1799.

Received 27 March 2007 ,Revised 22 February 2008 ,Accepted 4 March 2008.

References 

  1. Wilson AD, Kent BE. The glass-ionomer cement, a new translucent cement for dentistry. J Appl Chem Biotechnol. 1971;21:313
  2. Wilson AD, McLean JW. Glass-ionomer cement. Chicago, USA: Quintessence Books; 1988;
  3. Crisp S, Ferner AJ, Lewis BG, Wilson AD. Properties of improved glass-ionomer cement formulations. J Dent. 1975;3:125–130
  4. Katsuyama S, Ishikawa T, Fujii B. Translated [into English]. In:  Diehnelt DE editors. Glass ionomer dental cement: the materials and their clinical use.. St. Louis, Tokyo: Ishiyaku EuroAmerican; 1993;
  5. Wilson AD, Nicholson JW. Acid–base cements: their biomedical and industrial applications. Cambridge: Cambridge University Press; 1993;
  6. Davidson CL. Advances in glass-ionomer cements. Chicago, USA: Quintessence Pub. Co.; 1999;
  7. Mount GF. An atlas of glass-ionomer cements: a clinician's guide. 2nd ed.. London: Martin Dunitz; 1994;
  8. McLean JW, Nicholson JW, Wilson AD. Proposed nomenclature for glass-ionomer dental cements and related materials London. Quintessence Int. 1994;25:587–589
  9. Wilson AD, Kent BE. A new translucent cement for dentistry, the glass ionomer cement. Brit Dent J. 1972;132:133–135
  10. Powers JM, Sakaguchi RL. Craig's restorative dental materials. 12th ed.. London: Elsevier Mosby; 2006;
  11. Wilson AD. Developments in glass-ionomer cements. Int J Prosth. 1989;2:438–446
  12. Katsuyama S, Ishikawa T, Fuji B. Glass ionomer dental cement: the materials and their clinical use. Saint Louis: Ishiyaku EuroAmerica; 1993;
  13. Anusavice KJ. Philips science of dental materials. 11th ed.. Saunders: Philadelphia; 2003;
  14. Smith DC. Polyacrylic acid-based cement: adhesion to enamel and dentin. Oper Dent. 1999;5:177–183
  15. Kent BE, Lewis BG, Wilson AD. Glass ionomer cement formulations: I The preparation of novel fluoroaluminosilicate glasses high in fluorine. J Dent Res. 1979;58:1607–1619
  16. Nicholson JW. Chemistry of glass-ionomer cements: a review. Biomaterials. 1998;6:485–494
  17. Crisp S, Lewis BG, Wilson AD. Gelation of polyacrylic acid aqueous solutions and the measurement of viscosity. J Dent Res. 1975;54:1173–1175
  18. McLean JW, Powis DR, Prosser HJ, Wilson AD. The use of glass ionomer cements in bonding composite resins to dentine. Brit Dent J. 1985;158:410–414
  19. Culbertson BM. Glass-ionomer dental restoratives. Prog Polym Sci. 2001;26:577–604
  20. Xie D, Culbertson BM, Johntson WM. Improved flexural strength of N-vinylpyrrolidone modified acrylic acid copolymers for glass–ionomers. J.M.S. Pure Appl Chem. 1998;35:1615–1629
  21. Lucas ME, Arita K, Nishino M. Strengthening using a conventional glass ionomer cement hydroxyapatite. Biomaterials. 2003;24:3787–3791
  22. Gu YW, Yap AUJ, Cheang P, Khor KA. Effects of incorporation of HA/ZrO2 into glass ionomer cement (GIC). Biomaterials. 2005;26:713–720
  23. Gu YW, Yap AUJ, Cheang P, Khor KA. Development of zirconia-glass ionomer cement composites. J Non-Crystalline Solids. 2005;351:508–514
  24. Yamazaki T, Brantley BW, Culbertson BM, Seghi R, Schricker S. The measure of wear in N-vinyl pyrrolidinone (NVP) glass-ionomer cements. Polym Adv Technol. 2005;16:113–116
  25. Crisp S, Kent BE, Lewis BG, Ferner AJ, Wilson AD. Glass-ionomer cement formulations II. The synthesis of novel polycarobxylic acids. J Dent Res. 1980;59:1055–1063
  26. Kuriakose T, Kalkura N, Palanichamy M, Arivuoli D, Bocelli G, Betzel C. Synthesis of stoichiometric nano crystalline hydroxyapatite by ethanol-based sol–gel technique at low temperature. J Crys Growth. 2004;263:517–523
  27. Feng W, Mu-sen L, Yu-peng L, Yong Q. A simple sol–gel technique for preparing hydroxyapatite nanopowders. Mater Lett. 2005;59:916
  28. Cavalli M, Gnappi G, Montenero A, Fini M. Hydroxy- and fluorapatite films on Ti alloy substrates: sol–gel preparation and characterization. J Mater Sci. 2001;36:3253–3260
  29. Aknimade AO, Nicholson JW. Poisson's ratio of glass polyalkenoate cements determined by an ultrasonic methods. J Mater Sci Mater Med. 1995;6:1573–4838
  30. Rehman I, Bonfield W. Characterization of hydroxyapatite and carbonated apatite by photo acoustic FTIR spectroscopy. J Mater Sci: Mater Med. 1997;8:1–4
  31. Nikčević I, Jokanović V, Mitrić M, Nedić Z, Makovec D, Uskoković D. Mechanochemical synthesis of nanostructured fluorapatite/fluorhydroxyapatite and carbonated fluorapatite/fluorhydroxyapatite. J Sol Stat Chem. 2004;17:2565–2574
  32. Redey S, Nardin M, Bernache-Assolant D, Rey C, Delannoy P, Sedel L, et al. Behavior of human osteoblastic cells on stoichiometric hydroxyapatite and type A carbonate apatite: role of surface energy. J Biomed Mater Res. 2000;50:353
  33. Wei W, Evans JH, Bostrom T, Grondahl L. Synthesis and characterization of hydroxyapatite, fluoride-substituted hydroxyapatite and fluorapatite. J Mater Sci. 2003;14:311–320
  34. Culbertson BM. New polymeric materials for use in glass-ionomer cements. J Dent. 2006;34:556–565
  35. Xie D, Culbertson BM, Wang G. Microhardness of N-vinylpyrrolidone modified glass–ionomers cements.. J Macromol Sci Pure Appl Chem. 1998;35:547–561
  36. Yap AUJ, Pek YS, Kumar RA, Cheang P, Khor KA. Experimental studies on a new bioactive material: HA Ionomer cements. Biomaterials. 2002;23:955–962
  37. Moshaverinia A, Ansari S, Moshaverinia M, Roohpour N, Darr JA, Rehman IU. Effects of incorporation of hydroxyapatite and fluoroapatite nano-bioceramics into conventional glass-ionomer cements (GIC). Acta Biomater. 2008;4:432–440

PII: S0109-5641(08)00064-X

doi: 10.1016/j.dental.2008.03.008

Dental Materials
Volume 24, Issue 10 , Pages 1381-1390 , October 2008