Dental Materials
Volume 24, Issue 8 , Pages 1017-1024 , August 2008

Kinetic model for the coupled volumetric and thermal behavior of dental composites

  • Christof Koplin

      Affiliations

    • Biomedical Materials and Implants group, Fraunhofer-Institute for Mechanics of Materials, Freiburg, Germany
    • ,
  • Raimund Jaeger

      Affiliations

    • Biomedical Materials and Implants group, Fraunhofer-Institute for Mechanics of Materials, Freiburg, Germany
    • Corresponding Author InformationCorresponding author at: Biomedical Materials and Implants group, Fraunhofer - Institute for Mechanics of Materials, Wöhlerstr. 11, 79108 Freiburg, Germany. Tel.: +49 761 5142 284; fax: +49 761 5142 403.
    • ,
  • Petra Hahn

      Affiliations

    • Department of Operative Dentistry and Periodontology, Dental School and Hospital, Albert-Ludwigs-University, Freiburg, Germany

Received 6 September 2006 ,Revised 9 November 2007 ,Accepted 21 November 2007.

References 

  1. Mollica F, Santis R, Ambrosio L, Nicolais L, Prisco D, Rengo S. Mechanical and leakage behaviour of the dentin—adhesive interface. J Mater Sci Mater Med. 2004;4:485–492
  2. Watts DC, Marouf AS, Al-Hindi AM. Photo-polymerization shrinkage-stress kinetics in resin-composites: methods development. Dent Mater. 2003;19:1–11
  3. Manhart J, Kunzelmann KH, Chen HY, Hickel R. Mechanical properties of new composite restorative materials. J Biomed Mater Res. 2000;53:353–361
  4. Chen HY, Manhart J, Hickel R, Kunzelmann KH. Polymerization contraction stress in light-cured packable composite resins. Dent Mater. 2001;17:253–259
  5. Hofmann N, Markert T, Hugo B, Klaiber B. Effect of high intensity vs. soft-start halogen irradiation on temperature rise, polymerization contraction, hardness and solubility of photo-activated resin-based composites. Am J Dent. 2003;16(6):421–430
  6. Uhl A, Mills RW, Jandt KD. Photoinitiator dependent composite depth of cure and Knoop hardness with halogen and LED light curing units. Biomat. 2003;24:1787–1795
  7. Moszner N, Salz U. New developments of polymeric dental composites. Prog Polym Sci. 2001;26:535–576
  8. Lange J, Altmann N, Kelly CT, Halley PJ. Gelation behaviour during chainwise crosslinking polymerisation of methacrylate resins. Polymer. 1999;40:5699–5707
  9. Andrzejewska E. Photopolymerization kinetics of multifunctional monomers. Prog Polym Sci. 2001;26:605–665
  10. Anseth KS, Bowman CN. Kinetic gelation model predictions of crosslinked polymer network microstructure. Chem Eng Sci. 1994;49(14):2207–2217
  11. Ghiass M, Rey AD, Dabir B. Microstructure evolution and simulation of copolymerization reaction using percolation kinetic gelation model. Polymer. 2002;43:989–995
  12. Stansbury JW, Dickens SH. Network formation and compositional drift during photo-initiated copolymerization of dimethacrylate monomers. Polymer. 2001;42:6363–6369
  13. Atai M, Watts DC. A new kinetic model for the photopolymerization shrinkage-strain of dental composites and resin-monomers. Dent Mater. 2006;22:785–791
  14. Soltész U, Koplin C. Polymerisationsschrumpfung neuer Komposit-Füllungswerkstoffe. ZM. 2004;8:982–988
  15. Weidmann A. Polymerisationsschrumpfung, Wasseraufnahme und Quellung von lichthärtenden Komposit-Füllungsmaterialien. Med. Diss, Freiburg, 1987.
  16. Ikas K. Untersuchung der Polymerisationsschrumpfung von lichthärtenden und selbsthärtenden Kompositen mit Hilfe der hydrostatischen Wägung unter Variation der Bestrahlungsparameter. Med. Diss, Freiburg, 2006
  17. Uhl A, Mills RW, Jandt KD. Polymerization and light-induced heat of dental composites cured with LED and halogen technology. Biomaterial. 2003;24:1809–1820
  18. Uhl A, Mills RW, Rzanny AE, Jandt KD. Time dependence of composite shrinkage using halogen and LED light curing. Dent Mater. 2005;21:278–286
  19. Lim BS, Ferracane JL, Sakaguchi RL, Condon JR. Reduction of polymerization contraction stress for dental composites by two-step light-activation. Dent Mater. 2002;18:436–444
  20. Feilzer AJ, de Gee AJ, Davidson CL. Quantitative determination of stress reduction by flow in composite restorations. Dent Mater. 1990;6:167–171
  21. Dauvillier BS, Aarnts MP, Feilzer AJ. Modeling of the viscoelastic behaviour of dental light-activates resin composites during curing. Dent Mater. 2003;19:277–285

PII: S0109-5641(07)00281-3

doi: 10.1016/j.dental.2007.11.023

Dental Materials
Volume 24, Issue 8 , Pages 1017-1024 , August 2008

Article Tools

* Image Usage & Resolution