Dental Materials
Volume 22, Issue 6 , Pages 506-514 , June 2006

A novel amphiphilic acrylic copolymer based on Triton X-100 for a poly(alkenoate) glass-ionomer cement

  • E. Larraz

      Affiliations

    • Instituto de Ciencia y Tecnología de Polímeros, Juan de la Cierva 3, 28006 Madrid, Spain
    • ,
  • S. Deb

      Affiliations

    • Department of Biomaterials, GKT Dental Institute, King's College London, Floor 17 Guy's Tower, Guy's Campus, London Bridge, London SE1 9RT, UK
    • Corresponding Author InformationCorresponding author. Tel.: +44 20 7188 1817; fax: +44 20 7188 1823.
    • ,
  • C. Elvira

      Affiliations

    • Instituto de Ciencia y Tecnología de Polímeros, Juan de la Cierva 3, 28006 Madrid, Spain
    • ,
  • J. San Román

      Affiliations

    • Instituto de Ciencia y Tecnología de Polímeros, Juan de la Cierva 3, 28006 Madrid, Spain

Received 21 March 2005 ,Revised 17 May 2005 ,Accepted 16 June 2005.

References 

  1. Nicholson JW. Glass-ionomers in medicine and dentistry. Proc Inst Mech Eng [H]. 1998;212(2):121–126
  2. Wilson AD, McLean JW. Glass-ionomer cement. Chicago, IL: Quintessence Publishers; 1998;
  3. Wilson AD, Hill RG, Warren CP, Lewis BG. The influence of polyacid molecular weight on some properties of glass-ionomer cements. J Dent Res. 1989;68:69–94
  4. Culbertson BM. Glass-ionomer dental restoratives. Prog Polym Sci. 2001;26:577–604
  5. Kim SY, Shin IG, Lee YM. Amphiphilic diblock copolymeric nanospheres composed of methoxy poly(ethylene glycol) and glycolide: properties, cytotoxicity and drug release behaviour. Biomaterials. 1999;20:1033–1042
  6. Cölfen H. Double-hydrophilic block copolymers: synthesis and application as novel surfactants and crystal growth modifiers. Macromol Rapid Commun. 2001;22:219–252
  7. Suggs LS, Krishnan RS, García A, Peter SJ, Anderson JM, Mikos AG. J Biomater Sci Polym Ed. 1998;9:653
  8. Guo S, Shen L, Feng L. Surface characterization of blood compatible amphiphilic graft copolymers having uniform poly(ethylene oxide) side chains. Polymer. 2001;42(3):1017–1022
  9. Larraz E, Elvira C, San Román J. Novel acrylic macromonomer with amphiphilic character derived from Triton X-100: radical copolymerization with methyl methacrylate and thermal properties. J Polym Sci Polym Chem. 2003;41:1641–1649
  10. Bovis SC, Harrington E, Wilson HJ. Setting characteristic of composite filling materials. Br Dent J. 1971;131:352–356
  11. Lindman B, Alexandridis P. In:  Alexandridis P,  Lindman B editor. 1st ed. Amphiphilic block copolymers. vol. 1:Amsterdam: Elsevier; 2000;p. 1–12
  12. van Os NM. In:  van Os NM,  Haak JR,  Rupert LAM editor. Physico-chemical properties of selected anionic, cationic and nonionic surfactants. Amsterdam: Elsevier; 1993;
  13. Teoderescu M. Synthesis of (vinyl acetate)-terminated polystyrene macromonomers by free-radical polymerization in the presence of vinyl iodoacetate. Eur Polym. 2001;37:1417–1422
  14. Businelli L, Deleuze H, Gnanou Y, Maillard B. Amphiphilic block copolymers using miscellaneous ω-functional poly(ethylene oxide)'s as transfer agent. Macromol Chem Phys. 2000;201(14):1833–1839
  15. Jayachandran KN, Maiti S. Probing the association behavior of poly(ethyleneglycol) based amphiphilic comb-like polymer in the presence of cationic surfactant. Polymer. 2002;43:2349–2355
  16. Liu S, Sisson TM, O'Brien DF. Synthesis and polymerization of heterobifunctional amphiphiles to cross-link supramolecular assemblies. Macromolecules. 2001;34:465–473
  17. Xie H-Q, Liu Y. Synthesis, characterization and properties of amphiphilic poly(ethyl acrylate) with uniform polyoxyethylene grafts. J Appl Polym Sci. 2001;80:903–912
  18. Maniruzzaman M, Kawaguchi S, Ito K. Micellar copolymerization of styrene with a poly(ethylene oxide) macromonomer in water to a unimolecular graft copolymer micelle. Des Monomers Polym. 2001;3(3):255–261
  19. Nicholson JW. Chemistry of glass-ionomer cements: a review. Biomaterials. 1998;19(6):485–494
  20. Deb S, Shah P, Vazquez B, San Román J. A novel acrylic copolymer for a poly(alkenoate) glass-ionomer cement. J Mater Sci Mater Med. 2003;14:575–581
  21. Young AM, Rafeeka SA, Howlett JA. FTIR investigation of monomer polymerisation and polyacid neutralisation kinetics and mechanisms in various aesthetic dental restorative materials. Biomaterials. 2004;25(5):823–833
  22. Brook IM, Hatton PV. Glass-ionomers: bioactive implant materials. Biomaterials. 1998;19(6):565–571
  23. Hatton PV, Brook IM. Characterisation of the ultrastructure of glass-ionomer (poly-alkenoate) cement. Br Dent J. 1992;173(8):275–277

PII: S0109-5641(05)00223-X

doi: 10.1016/j.dental.2005.06.003

Dental Materials
Volume 22, Issue 6 , Pages 506-514 , June 2006

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