Dental Materials
Volume 22, Issue 4 , Pages 359-365 , April 2006

Volume contraction in photocured dental resins: The shrinkage-conversion relationship revisited

  • Magali Dewaele

      Affiliations

    • Ecole de Médecine Dentaire et de Stomatologie, Université catholique de Louvain, Bruxelles, Belgium
    • Unité de Chime et de Physique des Hauts Polymères, Université catholique de Louvain, Place Croix du Sud, 1 - Bât. Boltzmann, B-1348 Louvain-la-Neuve Belgium
  • ,
  • Delphine Truffier-Boutry

      Affiliations

    • Ecole de Médecine Dentaire et de Stomatologie, Université catholique de Louvain, Bruxelles, Belgium
    • Unité de Chime et de Physique des Hauts Polymères, Université catholique de Louvain, Place Croix du Sud, 1 - Bât. Boltzmann, B-1348 Louvain-la-Neuve Belgium
  • ,
  • Jacques Devaux

      Affiliations

    • Unité de Chime et de Physique des Hauts Polymères, Université catholique de Louvain, Place Croix du Sud, 1 - Bât. Boltzmann, B-1348 Louvain-la-Neuve Belgium
    • Corresponding Author InformationCorresponding author. Tel.: +32 10 47 35 56; fax: +32 10 45 15 93.
  • ,
  • Gaëtane Leloup

      Affiliations

    • Ecole de Médecine Dentaire et de Stomatologie, Université catholique de Louvain, Bruxelles, Belgium

Received 26 October 2004 ,Accepted 24 March 2005.

References 

  1. Loshaek S, Fox TG. Cross-linked polymers. I. Factors influencing the efficiency of cross-linking in copolymers of methylmethacrylate and glycol dimethacrylates. J Am Chem Soc. 1953;75:3544–3550
  2. Patel MP, Braden M, Davy KWM. Polymerization shrinkage of methacrylate esters. Biomaterials. 1987;8(1):53–56
  3. Venhoven BAM, de Gee AJ, Davidson CL. Polymerization contraction and conversion of light-curing Bis-GMA-based methacrylate resins. Biomaterials. 1993;14(11):871–875
  4. Bowen RL, Nemoto K, Rapson JE. Adhesive bonding of various materials to hard tooth tissues: forces developing in composite materials during hardening. J Am Dent Assoc. 1983;106(4):475–477
  5. Davidson CL, de Gee AJ, Feilzer A. The competition between the composite-dentin bond strength and the polymerization contraction stress. J Dent Res. 1984;63(12):1396–1399
  6. Davidson CL, Feilzer AJ. Polymerization shrinkage and polymerization shrinkage stress in polymer-based restoratives. J Dent. 1997;25(6):435–440
  7. Suliman AH, Boyer DB, Lakes RS. Polymerization shrinkage of composite resins: comparison with tooth deformation. J Prosthet Dent. 1994;71(1):7–12
  8. Jorgensen KD, Asmussen E, Shimokobe H. Enamel damages caused by contracting restorative resins. Scand J Dent Res. 1975;83(2):120–122
  9. Meredith N, Setchell DJ. In vitro measurement of cuspal strain and displacement in composite restored teeth. J Dent. 1997;25(3–4):331–337
  10. Roberts JC, Powers JM, Craig RG. Fracture toughness of composite and unfilled restorative resins. J Dent Res. 1977;56(7):748–753
  11. Bausch JR, de Lange K, Davidson CL, Peters A, de Gee AJ. Clinical significance of polymerization shrinkage of composite resins. J Prosthet Dent. 1982;48(1):59–67
  12. Peutzfeld A, Asmussen E. Determinants of in vitro gap formation of resin composites. J Dent. 2004;32(2):109–115
  13. Feilzer AJ, de Gee AJ, Davidson CL. Curing contraction of composites and glass-ionomer cements. J Prosthet Dent. 1988;59(3):297–300
  14. Labella R, Lambrechts P, Van Meerbeek B, Vanherle G. Polymerization shrinkage and elasticity of flowable composites and filled adhesives. Dent Mater. 1999;15(2):128–137
  15. Dauvillier BS, Feilzer AJ, de Gee AJ, Davidson CL. Visco-elastic parameters of dental restorative materials during setting. J Dent Res. 2000;79(3):818–823
  16. Dauvillier BS, Aarnst MP, Feilzer AJ. Modeling of the viscoelastic behavior of dental light-activated resin composites during curing. Dent Mater. 2003;19:277–285
  17. van Noort R, Cardew GE, Howard IC. A study of the interfacial shear and tensile stresses in a restored molar tooth. J Dent. 1988;16:286–293
  18. Braga RR, Ferracane JL. Contraction stress related to degree of conversion and reaction kinetics. J Dent Res. 2002;81(2):114–118
  19. Uno S, Asmussen E. Marginal adaptation of a restorative resin polymerized at reduced rate. Scand J Dent Res. 1991;99(5):440–444
  20. Deligeorgi V, Mjör IA, Wilson NHF. An overview of reasons for the placement and replacement of restorations. Primary Dent Care. 2001;8(1):5–11
  21. McInnis WA, Ismail A, Brogan H. Placement and replacement of restorations in military population. J Can Dent Asso. 1991;57(3):227–231
  22. Qvist V, Qvist J, Mjör IA. Placement and longevity of tooth-colored restorations in Denmark. Acta Odontol Scand. 1990;48(5):305–311
  23. Qvist V. Resin restorations: leakage, bacteria, pulp. Endodontics Dent Traumatol. 1993;9(4):127–152
  24. Tobolsky AV, Leonard F, Roeser GP. Use of polymerizable ring compounds in constant-volume polymerizations. J Polym Sci. 1948;3:604–606
  25. Peutzfeld A. Resin composites in dentistry: the monomer systems. Eur J Oral Sci. 1997;105(2):97–116
  26. Truffier-Boutry D, Demoustier-Champagne S, Devaux J, Biebuyck JJ, Mestdagh M, Larbanois P, et al., A physico-chemical explanation of the post-polymerization shrinkage in dental resins. Submitted for publication.
  27. de Gee AJ, Feilzer AJ, Davidson CL. True linear polymerization shrinkage of unfilled resins and composites determined with a linometer. Dent Mater. 1993;9(1):11–14
  28. Silikas N, Eliades G, Watts DC. Light intensity effects on resin-composite degree of conversion and shrinkage strain. Dent Mater. 2000;16(4):292–296
  29. Rueggeberg F, Tamareselvy K. Resin cure determination by polymerization shrinkage. Dent mater. 1995;11(4):265–268
  30. Linden LA, Jakubiak J. Contraction (shrinkage) in polymerization. Part II. Dental resin composites. Polimery. 2001;46(9):590–595
  31. Asmussen E. Restorative resins: hardness and strength vs. quantity of remaining double bonds. Scand J Dent Res. 1982;90(6):484–490
  32. Ferracane JL. Correlation between hardness and degree of conversion during the setting reaction of unfilled dental restorative resins. Dent Mater. 1985;1(1):11–14
  33. Ferracane JL, Greener EH. The effect of resin formulation on the degree of conversion and mechanical properties of dental restorative resins. J Biomed Mater Res. 1986;20(1):121–131
  34. Baharav H, Brosh T, Pilo R, Cardash H. Effect of irradiation time on tensile properties of stiffness and strength of composites. J Prosthet Dent. 1997;77(5):471–474
  35. Ferracane JL, Mitchem JC, Condon JR, Todd R. Wear and marginal breakdown of composites with various degrees of cure. J Dent Res. 1997;76(8):1508–1516
  36. Ferracane JL. Elution of leachable components from composites. J Oral Rehabil. 1994;21(4):441–452
  37. Pianelli C, Devaux J, Bebelman S, Leloup G. The micro-raman spectroscopy, a useful tool to determine the degree of conversion of light-activated composite resins. J Biomed Mater Res. 1999;48:675–681
  38. Asmussen E, Peutzfeldt A. Influence of UEDMA, BisGMA and TEGDMA on selected mechanical properties of experimental resin composites. D Mater. 1998;14(1):51–56
  39. Ferracane JL, Greener EH. Fourier transform infrared analysis of degree of polymerization in unfilled resins: methods comparison. J Dent Res. 1984;63(8):1093–1095
  40. Munksgaard EC, Hansen EK, Kato H. Wall-to-wall polymerization contraction of composite resins versus filler content. Scand J Dent Res. 1987;95(6):526–531
  41. Truffier-Boutry D, Gallez XA, Demoustier-Champagne S, Devaux J, Mestdagh M, Champagne B, et al. Identification of free radicals trapped in solid methacrylated resins. J Polym Sci Part A: Polymer Chemistry. 2003;41(11):1691–1699
  42. Cook WD. Photopolymerization kinetics of dimethacrylates using the camphorquinone/amine initiator system. Polymer. 1992;33(3):600–609

PII: S0109-5641(05)00185-5

doi: 10.1016/j.dental.2005.03.014

Dental Materials
Volume 22, Issue 4 , Pages 359-365 , April 2006